Diphosphine ligand chelation and bridging and regiospecific ortho metalation in the reaction of 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) with Ir4(CO)12: X-ray diffraction structures of Ir4(CO)7(μ-CO)3(bpcd), Ir4(CO)5(μ-CO)3(bpcd)(μ-bpcd), and HIr4(CO)4(μ-CO)3(bpcd)[μ-PhP(C6H4)CC(PPh2)C(O)CH2C(O)]-Reference-Cited by-同舟云学术

Diphosphine ligand chelation and bridging and regiospecific ortho metalation in the reaction of 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) with Ir4(CO)12: X-ray diffraction structures of Ir4(CO)7(μ-CO)3(bpcd), Ir4(CO)5(μ-CO)3(bpcd)(μ-bpcd), and HIr4(CO)4(μ-CO)3(bpcd)[μ-PhP(C6H4)CC(PPh2)C(O)CH2C(O)]

Published:2008-04 Issue:8-9 Volume:693 Page:1439-1448
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Watson William H.,Wu Guanmin,Richmond Michael G.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference79 articles.

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4. Kinetic studies of ligand substitution for carbon monoxide on dodecacarbonyltetrairidium, Ir4(CO)12

5. Ligand substitution processes in tetranuclear carbonyl clusters. 4. Molecular structure and reactivity of octacarbonyltetrakis(trimethylphosphine)tetrairidium

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4. Ligand substitution behavior of Ru6(μ6-C)(CO)17 with unsaturated diphosphines: facile capping of a polyhedral face and photochemically promoted P–C bond cleavage in the clusterRu6(μ6-C)(CO)14(μ3-bpcd);Dalton Trans.;2010

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