The reaction of Ru3(CO)12 with 1,4-dichloro-but-2-yne in basic methanolic solution. Synthesis and crystal structure of (μ-H)2Ru3(CO)9{μ3-η2-[H2CC(H)CCC(O)OCH3]}

Author:

Gervasio Giuliana,Marabello Domenica,Sappa Enrico,Secco Andrea

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference34 articles.

1. Formation of an allylic cluster in the reactions of [Ru3(CO)12] with diethylamino-propyne and trimethylsilyl propargyl alcohol. Crystal structure of [(μ-H)Ru3(CO)9(μ3-η3-C3H3)]

2. Reaction of Ru3(CO)12 with but-2-yn-1,4-diol in CH3OH/KOH solution. Crystal structure of (μ-Cl)Ru3(CO)9[μ3-η4-H2CCC(H)CH2]

3. G. Gervasio, D. Marabello, E. Sappa, A. Secco, manuscript in preparation

4. SHELXTL, Version 5.1;Sheldrick,1997

5. SMART, SAINT, SADABS, XPREP Software for CCD diffractometers, Bruker AXS Inc., Madison, WI

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