A synthetic, structural and reactivity study of [(η4-C4R4)Co(η5-C5H4X)] complexes, R=Me or Et; X=CHO, CHCHFc, CHCH(η5-C5H4)Co(η4-C4Ph4), CHC(CN)2: Unexpected formation of [(η5-cyclopentadienyl)(η4-3,4,5,6-tetraethyl-α-pyrone)cobalt]-Reference-Cited by-同舟云学术

A synthetic, structural and reactivity study of [(η4-C4R4)Co(η5-C5H4X)] complexes, R=Me or Et; X=CHO, CHCHFc, CHCH(η5-C5H4)Co(η4-C4Ph4), CHC(CN)2: Unexpected formation of [(η5-cyclopentadienyl)(η4-3,4,5,6-tetraethyl-α-pyrone)cobalt]

Published:2009-07 Issue:16 Volume:694 Page:2536-2547
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

O’Donohue Paul,Brusey Sarah A.,Seward Corey M.,Ortin Yannick,Molloy Bevin C.,Müller-Bunz Helge,Manning Anthony R.,McGlinchey Michael J.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference64 articles.

1. An NMR study of the rotational barriers in cobalt-stabilized carbocations: X-ray crystal structures of (η4-C4Ph4)Co-(η5-C5H4R), where R is CH3CO, CHO, CH(tBu)OH

2. McMurry reactions of (η5-acetylcyclopentadienyl) cobalt-(η4-tetraphenylcyclobutadiene) with benzophenone: ketone couplings and a pinacol/pinacolone rearrangement

3. Aldol condensation reactions of [Co(η4-C4Ph4){η5-C5H4C(O)CH3}]

4. pKa Prediction for Organic Acids and Bases;Perrin,1981

5. Ein Derivat des Cyclobutadiens

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