Rhodium(III) cationic methyl complexes containing dimethylformamide ligand, cis-[Rh(β-diket)(PPh3)2(CH3)(DMF)][BPh4] (β-diket = acetylacetonate or benzoylacetonate), in comparison with their acetonitrile analogs-Reference-Cited by-同舟云学术

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Rhodium(III) cationic methyl complexes containing dimethylformamide ligand, cis-[Rh(β-diket)(PPh3)2(CH3)(DMF)][BPh4] (β-diket = acetylacetonate or benzoylacetonate), in comparison with their acetonitrile analogs

Published:2014-12 Issue: Volume:774 Page:1-5
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Shestakova Elizaveta P.,Varshavsky Yuri S.,Khrustalev Victor N.,Starova Galina L.,Smirnov Sergei N.

Funder

Saint-Petersburg State University

Russian Academy of Sciences

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference24 articles.

1. Cationic methyl complexes of rhodium(III): synthesis, structure, and some reactions

2. Reactivity of cationic methyl rhodium(III) complexes cis-[Rh(β-diket)(PPh3)2(CH3)(CH3CN)][BPh4] toward ligands of different character: pyridine, carbon monoxide, and triphenylphosphine

3. Trifluoroacetylacetonate rhodium(III) methyl complexes, cis-[Rh(TFA)(PPh3)2(CH3)(L)][BPh4] and cis-[Rh(TFA)(PPh3)2(CH3)(I)] (L=CH3CN, NH3, pyridine), in comparison with their acetylacetonate analogs

4. Synthesis and characterization of acetamidine rhodium(III) cationic methyl complex, trans-[Rh(Acac)(PPh3)2(CH3){NHC(NH2)CH3}][BPh4], produced by ammination of acetonitrile ligand in trans-[Rh(Acac)(PPh3)2(CH3)(CH3CN)][BPh4]

5. Synthesis, characterization, and C–H activation reactions of novel organometallic O-donor ligated Rh(III) complexes

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