SnCl2 insertion into Ir–Cl and Rh–Cl bonds: Synthesis, characterization and catalytic activity of three-legged piano-stool trichlorostannyl iridium and rhodium complexes
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference57 articles.
1. Role of the trichlorostannate ligand in homogeneous catalysis. Mechanistic studies of the carbonylation of phenylplatinum(II) complexes
2. Role of the trichlorostannyl ligand in homogeneous catalysis. 2. Spectroscopic studies of the reaction of cis-[PtCl2(CO)(PR3)] with tin dichloride dihydrate (SnCl2.2H2O): ligand rearrangement reactions in the formation of an olefin hydroformylation catalyst precursor
3. Role of trichlorostannyl ligand in homogeneous catalysis. 3. Solvent effects on the reactions of cis-[PtCl2(L)(PR3)] and [Pt2(.mu.-Cl)2Cl2(PR3)2] (L = CO, SMe2; R = Ph, Et) with tin dichloride dihydrate (SnCl2.2H2O)
4. Role of the trichlorostannyl ligand in homogeneous catalysis. 4. Correlations of solution structure with catalytic activity in cis-[PtCl2(L)(PR3)]/ tin chloride dihydrate (SnCl2O) and [Pt2(.mu.-Cl)2Cl2(PR3)2]/ tin dichloride dihydrate (SnCl2.2H2O)(L = PR3, CO, thioether, amine; R = aryl, alkyl). Olefin hydrogenation and hydroformylation systems
5. Transition-metal complexes with derivatives of divalent silicon, germanium, tin, and lead as ligands
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