ALKYL DERIVATIVES OF OCTAHEDRAL MOLYBDENUM AND TUNGSTEN CLUSTER COMPLEXES
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Publisher
Elsevier
Reference8 articles.
1. Trirhenium(III) cluster alkyls. Synthesis of tertiary phosphine adducts; cleavage to rhenium-(III) and -(II) dimers; reactions with carbon monoxide, nitric oxide, and hydrogen chloride. X-Ray structural determinations of hexamethylbis(diethylphenylphosphine)tri-µ-methyl-triangulo-trirhenium(III) and tri-µ-chloro-(N-nitroso-N-trimethylsilyl-methylhydroxylaminato)pentakis(trimethylsilylmethyl)-triangulo-tri-rhenium(III)
2. The interaction of hydrogen with tri-µ-chloro-hexakis(trimethylsilylmethyl)-triangulo-trirhenium(III), its adducts with carbon monoxide, triphenylphosphine, and pyridine and with tri-µ-chloro-chloropentakis-(trimethylsilylmethyl)-triangulo-trirhenium(III). The X-ray crystal structures of hydridononakis(trimethylsilylmethyl)bis[tri-µ-chloro-triangulo-trirhenium(III)], tri-µ-chloro-chlorohydridotetrakis(trimethyl-silylmethyl)(triphenylphosphine)-triangulo-trirhenium(III), and syn,syn,-anti-trichloro-tris(µ-trimethylsilylmethyl)-tris(trimethylsilylmethyl)-triangulo-trirhenium(III)
3. Synthesis of hexanuclear molybdenum cluster alkyl complexes coordinated with trialkylphosphines: crystal structures of trans-[(Mo6Cl8)Cl4{P(n-C4H9)3}2] and all-trans-[(Mo6Cl8)Cl2(C2H5)2{P(n-C4H9)3}2].cntdot.2C6H5CH3
4. First synthesis of octahedral tungsten cluster chloro complexes with trialkylphosphines and their conversion to .eta.1-ethyl derivatives
5. T. Saito, unpublished results.
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