Completion of the alkali metal titanium (III) pyrophosphate series: Synthesis and structure of AITiP2O7 (AI = K, Rb, Cs)

Author:

Wang Shumin,Hwu Shiou-Jyh

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry,Condensed Matter Physics,Ceramics and Composites,Electronic, Optical and Magnetic Materials

Reference13 articles.

1. A new barium titanium (III) pyrophosphate: BaTi2(P2O7)2

2. Two forms of sodium titanium(III) diphosphate: α-NaTiP2O7 closely related to β-cristobalite and β-NaTiP2O7 isotypic with NaFeP2O7

3. LiTiP2O7: a = 4.891 (1) Å, b = 8.213 (1) Å, c = 6.962 (2) Å, β = 108.84 (2) Å, and V = 264.7 (2) Å3, monoclinic P21; S. Wang and S.-J. Hwu, Rice University, Houston, Texas, unpublished research (1990).

4. The pyrophosphate NaFeP2O7: A cage structure

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