Enantioselective synthesis of (2S4aS,8aR)-1,1,4a-trimethyldecahydronaphthalen-2-ol [(−)-TMD], (4aS,8aR)-5,5,8a-trimethyloctahydronaphthalen-2(1H)-one, and (−)-polywood®, through michael-type reaction of chiral imines-Reference-Cited by-同舟云学术

Enantioselective synthesis of (2S4aS,8aR)-1,1,4a-trimethyldecahydronaphthalen-2-ol [(−)-TMD], (4aS,8aR)-5,5,8a-trimethyloctahydronaphthalen-2(1H)-one, and (−)-polywood®, through michael-type reaction of chiral imines

Published:1997-04 Issue:7 Volume:8 Page:1101-1109
ISSN:0957-4166
Container-title:Tetrahedron: Asymmetry
language:en
Short-container-title:Tetrahedron: Asymmetry

Author:

Jabin Ivan,Revial Gilbert,Melloul Karine,Pfau Michel

Publisher

Elsevier BV

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis

Reference83 articles.

1. Enantioselective synthesis of quaternary carbon centers through Michael-type alkylation of chiral imines

2. Toward a transition-state model in the asymmetric alkylation of chiral ketone secondary enamines by electron-deficient alkenes. A theoretical MO study

3. A Theoretical Investigation of Enantioselectivity:Michael Reaction of Secondary Enamines with Enones

4. Diastereoselectivity in the Michael-Type Addition of Imines Reacting as Their Secondary Enamine Tautomers

5. Diastereoselectivity and enantioselectivity in the addition of chiral imines of 2-methylcyclohexanone to crotonic and methacrylic acid esters

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