A novel method for the asymmetric synthesis of 4,4-disubstituted 2-cyclopentenones from optically active 1-chlorovinyl p-tolyl sulfoxides and its application to the asymmetric total synthesis of (+)-α-cuparenone

Author:

Satoh Tsuyoshi,Yoshida Masaaki,Takahashi Yasuhiro,Ota Hiroyuki

Publisher

Elsevier BV

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis

Reference44 articles.

1. Some recent reviews and a monograph for construction of cyclic compounds including cyclopentanes and cyclopentenones: (a) Ho, T.-L. Carbocyclic Construction in Terpene Synthesis; VCH Publishers, Inc.: Weinheim. 1988; (b) Thebtaranonth, C.; Thebtaranonth, Y. Tetrahedron 1990, 46, 1385; (c) Petasis, N. A.; Patane, M. A. Tetrahedron 1992, 48, 5757; (d) Booker-Milburn, K. I.; Sharpe, A. J. Chem. Soc., Perkin Trans. 1 1998, 983; (e) Jankowski, P.; Marczak, S.; Wicha, J. Tetrahedron 1998, 54, 12071.

2. Vinylsilane- and alkynylsilane-terminated cyclization reactions

3. The khand reaction

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