Reductive amination of levulinic acid to different pyrrolidones on Ir/SiO 2 -SO 3 H: Elucidation of reaction mechanism

Author:

Martínez José J.,Silva Leonardo,Rojas Hugo A.,Romanelli Gustavo P.,Santos Lucas A.,Ramalho Teodorico C.,Brijaldo María H.,Passos Fabio B.

Funder

Colciencias (Colombia)

European Research Area Network; ERANet LAC

Publisher

Elsevier BV

Subject

General Chemistry,Catalysis

Reference27 articles.

1. L.E. Manzer, Production of 5-methyl-N-(methyl aryl)-2-pyrrolidone, 5-methyl-N-(methyl cycloalkyl)-2-pyrrolidone and 5-methyl-N-alkyl-2-pyrrolidone by reductive amination of levulinic acid with cyano compounds, US 6,841,520 B2, 2005.

2. L.E. Manzer, F.E. Herkes, Production of 5-methyl-1hydrocarbyl-2-pyrrolidone by reductive amination of levulinic acid, US2004/0192933, 2004.

3. [N-Methyl-2-pyrrolidone][C1-C4 carboxylic acid]: a novel solvent system with exceptional lignin solubility;Mu;Chem. Commun.,2015

4. Chemicals from biomass: chemoselective reductive amination of ethyl levulinate with amines;Vidal;ACS Catal.,2015

5. 1, 5-Dimethyl-2-Pyrrolidone;Robert;Org. Synth.,1947

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