Synthesis and characterization of the first series of isolable (nitro) ruthenium (III) complexes: a decomposition mechanism of the (nitro) ruthenium (III) moiety-Reference-Cited by-同舟云学术

Synthesis and characterization of the first series of isolable (nitro) ruthenium (III) complexes: a decomposition mechanism of the (nitro) ruthenium (III) moiety

Published:1996-04 Issue:2 Volume:245 Page:167-176
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Leising Randolph A.,Kubow Stephen A.,Szczepura Lisa F.,Takeuchi Kenneth J.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference41 articles.

1. Ligand Effect on the Electrochemical Oxidation oftrans-[Ru(NO2)X(py)4]n(n= 0 for X = NO2,n= + for X = NH3). Reactivity of Coordinated Nitro (RuII–NO2) to Give Monooxygen Moiety (RuIV=O) Depends on the Ambient Ligand (X)

2. Another Example of a Rare Reaction of Coordinated Nitro Ligand to Give Monooxygen Ligand. Fromtrans-[Ru(NO2)2(PY)4] totrans-[Ru(ONO)(O)(py)4]+

3. Nitro–Nitrito Isomerization Induced by Oxidation-Reduction of Central Metal Site: [RuII(NO2)(H2O)(py)4]+→←[RuIV(ONO)(O)(py)4]+

4. Selective formation of ruthenium(IV) complexes with a monooxygen ligand: trans-[RuX(O)(py)4]+ (X = Cl, ONO)

5. Temperature dependence of an oxygen transfer reaction induced by the oxidation of a nitro complex of ruthenium(II), trans-[RuCl(NO2)(py)4](py = pyridine)

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