Evidence of the interaction between steric and electronic influence in rhodoximes and cobaloximes. Synthesis of pyRh(DH)2I and X-ray structure of pyRh(DH)2Cl, pyCo(DH)2Cl and pyRh(DH)2I-Reference-Cited by-同舟云学术

Evidence of the interaction between steric and electronic influence in rhodoximes and cobaloximes. Synthesis of pyRh(DH)2I and X-ray structure of pyRh(DH)2Cl, pyCo(DH)2Cl and pyRh(DH)2I

Published:1994-02 Issue:1-2 Volume:216 Page:125-129
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Geremia Silvano,Dreos Renata,Randaccio Lucio,Tauzher Giovanni,Antolini Luciano

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference14 articles.

1. Organocobalt B12 models: axial ligand effects on the structural and coordination chemistry of cobaloximes

2. Structural properties of organocobalt coenzyme B12 models

3. Thermal decomposition and cobalt-carbon bond dissociation energies of organocobalamins: neopentyl-, (cyclopentylmethyl)-, (cyclohexylmethyl)-, (tetrahydrofurfuryl)- and ((tetrahydro-2H-pyryl)methyl)cobalamin

4. Thermolysis of the cobalt-carbon bond in adenosylcorrins. 3. Quantification of the axial base effect in adenosylcobalamin by the synthesis and thermolysis of axial base-free adenosylcobinamide. Insights into the energetics of enzyme-assisted cobalt-carbon bond homolysis

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