Stabilization and reaction behaviour of a terminal phosphido unit on a mononuclear Pt(II) centre. Synthesis and X-ray structure of a cationic diphenylphosphine complex [Pt{C6H3(CH2NMe2)2-2,6}(PHPh2)][OSO2CF3] and a diphenylphosphido-bridged Pt(II)/Pd(II) complex [Pt{C6H3(CH2NMe2)2-2,6}(μ-PPh2)Pd(C6H4CH2NMe2-2)-(H2O)][BF4]·CH2Cl2-Reference-Cited by-同舟云学术

Stabilization and reaction behaviour of a terminal phosphido unit on a mononuclear Pt(II) centre. Synthesis and X-ray structure of a cationic diphenylphosphine complex [Pt{C6H3(CH2NMe2)2-2,6}(PHPh2)][OSO2CF3] and a diphenylphosphido-bridged Pt(II)/Pd(II) complex [Pt{C6H3(CH2NMe2)2-2,6}(μ-PPh2)Pd(C6H4CH2NMe2-2)-(H2O)][BF4]·CH2Cl2

Published:1995-07 Issue:1-2 Volume:235 Page:327-338
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Maassarani Fida,Davidson Michael F.,Wehman-Ooyevaar Ingrid C.M.,Grove David M.,van Koten Martijn A.,Smeets Wilberth J.J.,Spek Anthony L.,van Koten Gerard

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

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4. 1,2-Methyl shift between platinum and the coordinated aryl group in the reaction of methyl iodide with 2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of platinum(II). X-ray crystal structure of the arenonium-platinum compound [Pt(o-tolyl)(MeC6H3(CH2NMe2)2-o,o')]I

5. M. Schmulling, D.M. Grove, G. van Koten, R. van Eldik, N. Veldman and A.L. Spek, manuscript including X-ray structure in preparation.

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