Reaction of Rh2(μ2-O2CCH3)3[μ2-(C6H4)PMePh](HO2CCH3)2 with triphenylphosphine: rearrangement of the metalated PMePh2 ligand and formation of a compound with a diphenylphosphinomethanide group in (P,C) coordination; crystal structure of [Rh2(μ2-O2CCH3)2{μ2-(CH2)PPh2}- {μ2-(C6H4)PPh2}(PPh3)]·2CH2Cl2-Reference-Cited by-同舟云学术

Reaction of Rh2(μ2-O2CCH3)3[μ2-(C6H4)PMePh](HO2CCH3)2 with triphenylphosphine: rearrangement of the metalated PMePh2 ligand and formation of a compound with a diphenylphosphinomethanide group in (P,C) coordination; crystal structure of [Rh2(μ2-O2CCH3)2{μ2-(CH2)PPh2}- {μ2-(C6H4)PPh2}(PPh3)]·2CH2Cl2

Published:1995-02 Issue:1-2 Volume:229 Page:365-371
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Estevan Francisco,García-Granda Santiago,Lahuerta Pascual,Latorre Julio,Peris Eduardo,Sanaú Mercedes

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference36 articles.

1. Structural and electrochemical characterization of the novel ortho-metalated dirhodium(II) compounds Rh2(O2CMe)2[Ph2P(C6H4)]2.cntdot.2L

2. Mechanisms of intramolecular activation of carbon-hydrogen bonds in transition-metal complexes

3. Ortho-metalation reactions in binuclear dirhodium compounds. Molecular structure and reactivity of a monometalated compound with the phosphine P(o-ClC6H4)(C6H5)2

4. Fast ortho-metalation reactions in binuclear dirhodium compounds. Syntheses and molecular structures of a monometalated compound and two doubly metalated compounds with head-to-head configurations

5. Fast orthometalation reactions at a binuclear dirhodium(II) complex. Synthesis, crystal structure and reactivity of Rh2(O2CCH3)3[(C6H4)PPh2]·(HO2CCH3)2

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