The ligand polyhedral model and its application to the fluxional behaviour of M4(CO)12−n (M Co, Rh, Ir; n = 1, 2, 4 clusters
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference32 articles.
1. Mechanistic features of metal cluster rearrangements
2. A Solution to the Structural Dilemma of Co4(CO)12Based on Valence Tautomerism and Steric Nonrigidity
3. Direct evidence from carbon-13 nuclear magnetic resonance for intramolecular scrambling of carbonyl groups in a metal atom cluster carbonyl, tetrarhodium dodecacarbonyl
4. Carbon-13 nuclear magnetic resonance spectra of polynuclear carbonyls of cobalt and rhodium
5. Intracluster ligand mobility. 4. Solution structures and dynamics of Ir4(CO)12-x(PPh2Me)x (x = 1-4)
Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Dynamic structure in supported Pt nanoclusters: Real-time density functional theory and x-ray spectroscopy simulations;Physical Review B;2008-09-11
2. Reaction of Alkynes with Rh4(CO)12. A Mid-Infrared Vibrational and Kinetic Study of (μ4-η2-alkyne)Rh4(CO)8(μ-CO)2;Organometallics;2006-03-21
3. Spectral resolution of fluxional organometallics. The observation and FTIR characterization of all-terminal [Rh4(CO)12];Dalton Transactions;2005
4. Structural redetermination of Rh-4(CO)(12) at 293 and 173 K and analysis of the thermal motion in relation to the dynamical behavior;Journal of Cluster Science;2000
5. Mixed Metal Cluster Chemistry. 10.1 Isomer Distribution and Ligand Fluxionality at CpWIr3(μ-CO)3(CO)8-n(PR3)n (n = 1, 2; R = Ph, Me);Organometallics;1999-07-10
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