Solvent cage effects. I. Effect of radical mass and size on radical cage pair recombination efficiency. II. Is geminate recombination of polar radicals sensitive to solvent polarity?

Author:

Braden Dale A.,Parrack Eileen E.,Tyler David R.

Publisher

Elsevier BV

Subject

Materials Chemistry,Physical and Theoretical Chemistry,Inorganic Chemistry

Reference88 articles.

1. Some remarks about free radicals and the photochemistry of solutions

2. The collison mechanism and the primary photochemical process in solutions

3. Collision, co-ordination, diffusion and reaction velocity in condensed systems

4. In addition to recombination and diffusive separation, the chemical reactions of cage pairs can include disproportionation, isomerizations, fragmentations, electron transfer, in-cage trapping, etc. For the metal–radical cage pairs in this paper, the only chemical process is kc.

5. T. Koenig, in: W.A. Pryor, (Ed.), Organic Free Radicals, ACS Symposium Series, vol. 69, 1978 (Chapter 9).

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