Oxidative addition of mercury(II) halides and carboxylates to platinum(II): formation of Pt–Hg covalent and donor–acceptor bonds
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference28 articles.
1. Synthesis of the Reagent [Na][Pt(PEt3)2(η5-7-CB10H11)] and Preparation of the Platinacarborane Complexes [PtX(PEt3)2(η5-7-CB10H11)] (X = H, Au(PPh3), Cu(PPh3), HgPh)
2. Synthesis and characterisation of new binuclear complexes containing a relatively strong Pt to Hg donor bond. Molecular structure of complex [Pt(C^P)(μ-O2CCH3)2Hg(O2CCH3)]
3. Reactivity of [M(C∧P)(acac-O,O‘)] [M = Pt, Pd; C∧P = CH2-C6H4-P(o-tolyl)2-κC,P; acac = 2,4-pentanedionato] toward HgX2 (X = Br, I, CH3COO, CF3COO). New Polynuclear Complexes Containing Pt−Hg Bonds. Molecular Structures of [{Pt(C∧P)(acac-O,O‘)- HgBr(μ-Br)}2(μ-HgBr2)], an Unprecedented Square-Planar Bromomercurate Complex, and [{Pt(C∧P)(μ-O2CCH3)2Hg(μ3-acac2--κC3,O)Hg(O2CCH3-κO)}· CHCl3]2, the First Complex Containing Asymmetric Dimercurated Acetylacetone
4. Reactivity of [M(C∧P)(S2C-R)] (M = Pd, Pt; C∧P = CH2-C6H4-P(o-tolyl)2-κC,P; R = NMe2, OEt) toward HgX2 (X = Br, I). X-ray Crystal Structures of [Pt{CH2-C6H4P(o-tolyl)2-κC,P}(S2CNMe2)HgI(μ-I)]2 and [PdBr(S2COEt){μ-P(o-tolyl)2-C6H4-CH2-}HgBr]·0.5HgBr2·C2H4Cl2
5. Mixed platinum(II)-mercury(II) cytosine nucleobase complexes with metal-metal bonds
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3. Reactions of Cycloplatinated Guanidine Complexes with Hg(OC(O)CF3)2: Formation of a One-Dimensional Coordination Polymer Containing a Pt2Hg(μ2-S(O)Me2-S,O) Repeating Unit versus a Discrete Pt2Hg2 Complex;Inorganic Chemistry;2021-03-04
4. Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal–Metal Bond;Inorganic Chemistry;2019-07-17
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