Synthesis and crystallographic characterization of dimeric perfluoroalkyl iridium complexes: [Cp∗Ir(X)(RF)]2 (X = I, RF= CF3, CF2CF3, CF2CF2CF3, CF(CF3)2, CF(CF3)(CF2CF3); X = Cl and Br, RF= CF2CF3), and a new perfluoroethylidene complex Cp∗Ir(PPh3)(CFCF3)
Author:
Funder
National Science Foundation
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference12 articles.
1. Syntheses and crystallographic studies of [Ir(η5-C5Me5)(L)(RF)I] (L = CO, PMe3; RF = CF2CF3, CF2CF2CF3, CF2C6F5, CF(CF3)2) complexes. Cone and solid angle steric parameters for perfluoroalkyl ligands
2. Conversion of Carbon–Fluorine Bonds α to Transition Metal Centers to Carbon–Hydrogen, Carbon–Carbon, and Carbon–Heteroatom Bonds
3. A Simple Route to Difluorocarbene and Perfluoroalkylidene Complexes of Iridium
4. α- and β-Fluorine Elimination Reactions Induced by Reduction of Iridium−Fluoroalkyl Complexes. Selective Formation of Fluoroalkylidene and Hydrofluoroalkene Ligands
5. The First Example of a Bis(trifluoromethyl)carbene Transition‐Metal Complex and Its Reduction to a Perfluoroallene Complex
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