Electronic structure of a benzylidyne-capped tricobalt cluster, [Co3Cp3(μ3-CPh)2]. X-ray structures and 1H NMR paramagnetic shifts of its cation and DFT calculations of its model complex-Reference-Cited by-同舟云学术

Electronic structure of a benzylidyne-capped tricobalt cluster, [Co3Cp3(μ3-CPh)2]. X-ray structures and 1H NMR paramagnetic shifts of its cation and DFT calculations of its model complex

Published:2004-01 Issue:2 Volume:357 Page:533-540
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Ebihara Masahiro,Iiba Masami,Kato Masayuki,Minami Hidehito,Kawamura Takashi

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference40 articles.

1. (Cyclopentadienyl) metal cluster complexes of the group 9 transition metals

2. Organometallic chalcogen complexes. XVII. Preparation and structural characterization of a metal-oxygen atom cluster system, Co3(.pi.-C5H5)3(CO)(O)

3. Organometallic chalcogen complexes. XXV. Structural and magnetic studies of Co3(h5-C5H5)3(CO)(S), Co3(h5-C5H5)3S2, and the oxidized monocation, [Co3(h5-C5H5)3S2]+. Sensitivity of the geometry of a triangular metal cluster system to antibonding electrons

4. Stereochemical and electrochemical analyses of the cyclopentadienyl and methylcyclopentadienyl dinitrosyl-capped tricobalt analogs, Co3(.eta.5-C5H5-xMex)3(.mu.3-NO)2 (where x = 0, 1), of the classical Fischer-Palm Ni3(.eta.5-C5H5)3(.mu.3-CO)2

5. Synthesis, structural-bonding-magnetic study, and proton NMR analysis of the temperature-dependent singlet-triplet solution equilibrium of the 46-electron tricobalt tris(pentamethylcyclopentadienyl) dicarbonyl, Co3(.eta.5-C5Me5)3(.mu.3-CO)2: an isolobal analog of the elusive antiaromatic cyclopropenyl monoanion

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1. The unexpected reactivity of 9-iodo-nido-carborane: from nucleophilic substitution reactions to the synthesis of tricobalt tris(dicarbollide) Na[4,4′,4′′-(MeOCH2CH2O)3-3,3′,3′′-Co3(μ3-O)(μ3-S)(1,2-C2B9H10)3];Dalton Transactions;2021

2. Trigonal Mn3 and Co3 Clusters Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic, and Computational Investigation into the Correlation of Molecular and Electronic Structure;Inorganic Chemistry;2012-09-19

3. Functions Containing Two Atoms of the Same Metallic Element;Comprehensive Organic Functional Group Transformations II;2005

4. Synthesis, structure, and formation mechanism of the halogen-bridged tricobalt clusters, [Co3Cp3(μ3-CPh)2(μ-X)]+ (X=Cl, Br, and I);Inorganica Chimica Acta;2004-03

5. Paramagnetic NMR;Nuclear Magnetic Resonance