High-pressure synthesis of [Ru2(μ-dppm)2 (μ-CO)(CO4, Ru2(μ-dppm)(μ-dmpm) (μ-CO)(CO4], and [Ru(dcypm)(CO)3] from Ru3(CO)12 and the diphosphines: R2PCH2PR2; R = CH3(dmpm), C6H5(dppm) and C6H11 (dcypm). Crystal and molecular structures of [Ru2(μ-dppm)2(μ-CO)(CO)4], and [Ru(dcypm)(CO)3]-Reference-Cited by-同舟云学术

High-pressure synthesis of [Ru2(μ-dppm)2 (μ-CO)(CO4, Ru2(μ-dppm)(μ-dmpm) (μ-CO)(CO4], and [Ru(dcypm)(CO)3] from Ru3(CO)12 and the diphosphines: R2PCH2PR2; R = CH3(dmpm), C6H5(dppm) and C6H11 (dcypm). Crystal and molecular structures of [Ru2(μ-dppm)2(μ-CO)(CO)4], and [Ru(dcypm)(CO)3]

Published:1997-01 Issue:9 Volume:16 Page:1453-1459
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Ferrence Gregory M.,Fanwick Phillip E.,Kubiak Clifford P.,Haines Raymond J.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference24 articles.

1. Synthesis and reactivity of the unsaturated diruthenium diphosphazane-bridged species [Ru2(CO)4{µ-(RO)2PN(Et)P(OR)2}2](R = Me or Pri)

2. Synthesis of the solvento species [Ru2(CO)5(solvent){μ- (RO)2PN(Et)P(OR)2}2]2+ and its potential as a source for a wide range of dinuclear derivatives of ruthenium

3. Reactions of diphosphazane-bridged derivatives of diruthenium nonacarbonyl with metal-containing electrophiles: formation of solvento species [Ru2(CO)5(solv){µ-(RO)2PN(Et)P(OR)2}2]2+(R = Me or Pri) and their reactivity towards various nucleophiles

4. Electrochemical behaviour of ditertiary phosphine and diphosphazane ligand-brdiged derivatives or di-iron and di-ruthenium nonacarbonyl

5. Stabilisation of [Fe2(CO)9] and [Ru2(CO)9] bu substitution with bridging diphosphorus ligands

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