Modified steroids: Pb(OAc)4 mediated one-pot multistage transformations of steroidal unsaturated 1,2-diols

Author:

del Rosario Rico Ferreira Maria,Martı́n Hernando José Ignacio,Candela Lena José Ignacio,Quı́lez del Moral José,Arseniyadis Siméon

Publisher

Elsevier BV

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis

Reference18 articles.

1. A-Homosteroids: Goldberg, M. W.; Kirchensteiner, H. Helv. Chim. Acta 1943, 26, 288; Velgová, H.; Cerny, V.; Sorm, F. Collect. Czech. Chem. Commun. 1973, 38, 2751–2759; B-Homosteroids: Ringold, H. J. J. Am. Chem. Soc. 1960, 82, 961–963; Kohut, L; Fajkos, J.; Sorm, F. Collect. Czech. Chem. Commun. 1967, 32, 1210–1228; Kohut, L. Collect. Czech. Chem. Commun. 1972, 37, 2227–2233; D-Homosteroids: Goldberg, M. W.; Monnier, R. Helv. Chim. Acta 1940, 23, 376, 840; A-nor-B-homosteroids: Suginome, H.; Yabe, T.; Osawa, E. J. Chem. Soc. Perkin Trans. 1 1982, 931–938.

2. 5α-Reductase is the NADPH-dependent enzyme which irreversibly converts testosterone to the more potent androgen dihydrotestosterone. Anderson, K. M.; Liao, S. Nature 1968, 219, 277; Imperato-McGinley, J.; Guerro, L.; Gautier, T.; Peterson, R. E. Science 1974, 186, 1213–1215; Bardin, C. W.; Catterall, J. F. Science 1981, 211, 1285.

3. Rasmusson, G. H.; Reynolds, G. F.; Steinberg, N. G.; Walton, E.; Patel, G. F.; Liang, T.; Cascieri, M. A.; Cheung, A. H.; Brooks, J. R.; Berman, C. J. Med. Chem. 1986, 29, 2298–2315.

4. Audet, P. R.; Baine, N. H.; Benincosa, L. J.; Holt, D. A.; Wier, P. J.; Rappaport, E. B.; Metcalf, B. W.; Levy, M. A. Drugs Fut 1994, 19, 646–650.

5. Tetrahedron Symposia-in-Print Number 62, Cascade Reactions, R. Grigg, Ed. 1996, 52, 11385–11664, and references cited therein.

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