Preparation and characterization of triply-bridged dinuclear copper(II) complexes containing the [Cu2(μ-OH)(μ-X)(μ-OAc)]+ core (X = Cl, Br), and the crystal structure of [Cu2(OH)Cl(OAc)(bpy)2](ClO4)

Preparation and characterization of triply-bridged dinuclear copper(II) complexes containing the [Cu2(μ-OH)(μ-X)(μ-OAc)]+ core (X = Cl, Br), and the crystal structure of [Cu2(OH)Cl(OAc)(bpy)2](ClO4) · H2O

Published:1991-01 Issue:19 Volume:10 Page:2301-2308
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Perlepes Spiros P.,Huffman John C.,Christou George

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference51 articles.

1. A new type of copper complex as found in the crystal structure of cupric acetate, Cu2(CH3COO)4.2H2O

2. Metal-metal bonding in dirhodium tetracarboxylates. Structure of the bis(diethylamine) adduct of tetra-.mu.-acetato-dirhodium(II) and systematics of the bonding in tetracarboxylate-bridged metal dimers

3. A novel variation on a classical dimeric structure type. Preparation and structure of the metal-nitroxyl complex [Cu(O2CCCl3)2(Tempo)]2

4. Interdimer exchange in linear chain copper acetate-pyrazine

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