Molybdenum(VI) complexes of branched ligands with [N,O,O,O] and [O,O,O] donor sets. The crystal and molecular structures of [MoO2{HOC2H4N(C2H4)O2}], [(n-C4H9)4N]2[Mo2O4{(O2NCCH2O)3}2]·202NC(CH2OH)3, [(n-C4H9)4N][Mo2O5{(HO2CCH2N)(CH2CO2)2}2]·H2O and [n-C4H9)4N][Mo3O6(OCH3{(CH3OCH2O)3}2]
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference34 articles.
1. The synthesis and structure of tetrasodium tetramethoxyoctamolybdate-methanol complex (Na4[Mo8O24(OCH3)4].8MeOH): a novel isopolymolybdate that decomposes with the loss of formaldehyde
2. Coordination complexes of polyoxomolybdate anions. Characterization of a tetranuclear core from reactions in methanol: syntheses and structures of two polyoxomolybdate alcoholates, (MePPh3)2[Mo4O10(OCH3)6] and (n-Bu4N)2[Mo4O10(OCH3)2(OC6H4O)2], and their relationship to a general class of tetranuclear cluster types [Mo4Ox(OMe)2(L)y(LL)z]2-
3. Polyoxomolybdate-alkoxide interactions. The crystal and molecular structures of the erythritolate complexes [(n-C4H9)4N]2[Mo2O5(eryth)] and [(n-C4H9)4N][Mo2O5(Heryth)]
4. A novel .beta.-ketophosphonate 1,4-dianion. Tin/lithium exchange
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