The chemistry of cobalt acetate. VIII. New members of the family of oxo-centred trimers, [Co3(μ3-O)(μ-O2CCH3)5−(μ-OR) L5]2+ (R=H, alkyl, L=ligand, p=0–4). The preparation and characterisation of the trimeric tetrakis(μ-acetato)-(μ-hydroxo)-μ3-oxo-pentakis(pyridine)-tri-cobalt(III) hexafluorophosphate, [Co3(μ3-O)(μ-O2CCH3)4(μ-OH)(C5H5N)5][PF6]2, and the preparation and crystal structure of the trimeric tris(μ-acetato)-(μ-hydroxo)-(μ-methoxo)-μ3-oxo-pentakis(pyridine)-tri-cobalt(III) hexafluorophosphate·methanol·water solvate [Co3(μ3-O)(μ-O2CCH3)3(μ-OH)(μ-OCH3)(C5H5N)5][PF6]2·CH3OH·0.25H2O-Reference-Cited by-同舟云学术

The chemistry of cobalt acetate. VIII. New members of the family of oxo-centred trimers, [Co3(μ3-O)(μ-O2CCH3)5−(μ-OR) L5]2+ (R=H, alkyl, L=ligand, p=0–4). The preparation and characterisation of the trimeric tetrakis(μ-acetato)-(μ-hydroxo)-μ3-oxo-pentakis(pyridine)-tri-cobalt(III) hexafluorophosphate, [Co3(μ3-O)(μ-O2CCH3)4(μ-OH)(C5H5N)5][PF6]2, and the preparation and crystal structure of the trimeric tris(μ-acetato)-(μ-hydroxo)-(μ-methoxo)-μ3-oxo-pentakis(pyridine)-tri-cobalt(III) hexafluorophosphate·methanol·water solvate [Co3(μ3-O)(μ-O2CCH3)3(μ-OH)(μ-OCH3)(C5H5N)5][PF6]2·CH3OH·0.25H2O

Published:2003-04 Issue:7 Volume:22 Page:947-965
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Beattie James K.,Klepetko John A.,Masters Anthony F.,Turner Peter

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference29 articles.

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2. Methodology and scope of metal/bromide autoxidation of hydrocarbons

3. Chemical accuracy and precision in Rietveld analysis: The crystal structure of cobalt(II) acetate tetrahydrate

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