Synthesis and structural characterization of the novel tetrahedral MNiFeS clusters containing functionally substituted cyclopentadienyl ligands (η5-RC5H4(η5-C5H5)MNiFeS(CO)5 (M = Mo, W ; R = CHO, CH3CO, CH3O2C, CH2OH, CH(OH)CH3, (NO2)2C6H3NHN). The crystal molecular structure of (η5-CHOC5H4(η5-C5H5)MoNiFeS(CO)5
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference20 articles.
1. Study on the reaction between metal-metal-bonded compounds [(.eta.5-RC5H4)M(CO)3]2 and Co2(CO)8. Synthesis and characterization of the tetrahedral clusters (.eta.5-RC5H4)M(CO)2Co3(CO)6(.mu.-CO)3 (M = Mo, W; R = Me3Si, C(O)Me, CO2Me, CO2Et)
2. Synthesis, Characterization, and Reactions of the Cluster Complexes Containing the Tetrahedral Cluster Core MFeCoS (M = Mo, W) and a Functionally Substituted Cyclopentadienyl Ligand. The Single Crystal X-ray Structures of Two Double Clusters, [.eta.5-C5H4C(O)CH2CH2C(O)C5H4-.eta.5][M(CO)2Fe(CO)3Co(CO)3(.mu.3-S)]2 (M = Mo, W)
3. The study of isolobal displacement reactions. Synthesis and characterization of heteronuclear transition-metal clusters [(η5-RC5H4)(CO)2M] [(η5-R′C5H4)(CO)2M′]Fe(CO)3(μ3-S), [(η5-R′C5H4)(CO)2M′]2Fe(CO)3(μ3-S) (M,M′ = Mo or W) and [(η5-MeO2CC5H4)(CO)2W] [(η5-MeC(O)C5H4)(CO)2W]Fe(CO)3(μ3-S)
4. The study of isolobal displacement reactions. Synthesis and structures of the heterobimetallic μ-alkyne cluster complexes η-RC5H4(CO)2M(μ-R1C2R2)Co(CO)3 (MMo, W; RCH3C(O), CH3O2C)
5. Synthesis, reactions and characterization of homo- and heterobimetallic Mo/W μ-alkyne complexes containing functionally substituted cyclopentadienyl ligands: The crystal structure of [ν5-MeO2CC5H4(CO)2MoW(CO)2C5H4Et-ν5](μ-C2H2)
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1. Unusual formation of a [NiSFe2(CO)6] cluster: a structural model for the inactive form of [NiFe] hydrogenase;Dalton Trans.;2009
2. Heterometallic Iron-containing Compounds;Comprehensive Organometallic Chemistry III;2007
3. Formation of [(L)Ni(μ2-S)x{Fe(CO)3}x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase;Chem. Commun.;2006
4. Syntheses and crystal structures of quadruply bridged Mo2Se4 complexes containing functionalized cyclopentadienyl ligands: trans/anti − (η5-CH3O2CC5H4)2Mo2(μ-Se)2(μ-SeCH2Ph)(μ-SePh) and trans/syn-(η5-C2H5O2CC5H4)2Mo2(μ-Se)2(μ-SePh)2;Journal of Coordination Chemistry;2004-06-15
5. Preparation and characterization of clusters containing the MNiRuS (M = Mo or W) core;Journal of Coordination Chemistry;2004-03-10
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