Synthesis of a rhodium methylthiolate and insertion of CS2 into the Rh—SCH3 bond. Structure of the thioxanthate [(pp3)RhSC(S)SCH3] [pp3 = tris(2-(diphenylphosphino)ethyl)phosphine]-Reference-Cited by-同舟云学术

Synthesis of a rhodium methylthiolate and insertion of CS2 into the Rh—SCH3 bond. Structure of the thioxanthate [(pp3)RhSC(S)SCH3] [pp3 = tris(2-(diphenylphosphino)ethyl)phosphine]

Published:1993-01 Issue:1 Volume:12 Page:13-17
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Di Vaira Massimo,Rovai Donella,Stoppioni Piero

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference32 articles.

1. Transition-metal complexes with sulfur ligands. 82. Hydrogen sulfide, disulfur, and carbon disulfide molecules as ligands in sulfur-rich [Ru(PPh3)('S4')] complexes [('S4')2- = 1,2-bis[(2-mercaptophenyl)thio]ethane(2-)]

2. Hydrido thiolato and thiolato complexes of ruthenium(II) carbonyl phosphines

3. Synthesis and reactivity of (pentamethylcyclopentadienyl)iridium bis(thiolate) and thiolate hydride complexes

4. Synthesis of new cyclopentadienyliron and -ruthenium benzenethiolate, thiol, and thio ether complexes

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1. Cyclopentadienyl ruthenium alkynyldithiocarboxylate complexes;Journal of Organometallic Chemistry;2006-04

2. Insertion Reactions of [M(SR)3(PMe2Ph)2] with CS2 (M = Ru, Os; R = C6F4H-4, C6F5). X-ray Structures of [Ru(S2CSC6F4H-4)2(PMe2Ph)2], trans-Thiolates [M(SR)2(S2CSR)(PMe2Ph)2] (M = Ru; R = C6F5 and M = Os; R = C6F4H-4), and trans-Thiolate−Phosphine [Os(SC6F5)2(S2CSC6F5)(PMe2Ph)2];Inorganic Chemistry;2004-01-13

3. Half sandwich iron S-bonded mono-thiocarbonate complexes: structure of CpFe(CO)2SCO2Et;Polyhedron;2003-10

4. Structural diversity in coordination chemistry of tridentate and tetradentate polyphosphines of Group 6 to 10 transition metal complexes;Coordination Chemistry Reviews;2003-01

5. 3. Rhodium 1993;Coordination Chemistry Reviews;1996-07