An approach to heterometallic alkoxide-β-diketonate complexes with a M4O4 cubane-like core and new prospects of their application in preparation of solid catalysts. X-ray single crystal study of (Co,Ni)4(acac)4(μ3-OMe)4(MeOH)4, Co2Ni2(acac)4(μ3-OMe)4(OAc)2 and Mg4(acac)4(μ3-OMe)4(MeOH)4-Reference-Cited by-同舟云学术

An approach to heterometallic alkoxide-β-diketonate complexes with a M4O4 cubane-like core and new prospects of their application in preparation of solid catalysts. X-ray single crystal study of (Co,Ni)4(acac)4(μ3-OMe)4(MeOH)4, Co2Ni2(acac)4(μ3-OMe)4(OAc)2 and Mg4(acac)4(μ3-OMe)4(MeOH)4

Published:2001-04 Issue:9-10 Volume:20 Page:915-922
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Kessler Vadim G,Gohil Suresh,Kritikos Mikael,Korsak Oksana N,Knyazeva Elena E,Moskovskaya Irina F,Romanovsky Boris V

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference17 articles.

1. Magnetic exchange in transition metal complexes. V. Ferromagnetic spin coupling in a tetranuclear nickel(II) cluster

2. Structural and Magnetic Properties of [Ni4(.mu.3-OMe)4(dbm)4(MeOH)4] and [Ni4(.eta.1,.mu.3-N3)4(dbm)4(EtOH)4]. Magnetostructural Correlations for [Ni4X4]4+ Cubane Complexes

3. The Case of a Cu4 Rhombus in Molecular Magnetism: Preparation, Crystal Structure, and Magnetic Properties of [Cu4(dpk·CH3O)4(CH3O)2](ClO4)2 (dpk·CH3OH = Monomethylated Diol of Di-2-pyridyl Ketone), an Example of a Cluster Allowing the Determination of All Its Exchange Parameters, Ranging from Very Strong to Very Weak

4. Synthesis and structural characterization of new copper complexes and the copper-barium-alkoxide complex BaCu4(OC(R)C(H)C(R)O)4(OR')2(HOR')4 (R = C(CH3)3, R' = CH2CH2OCH3)

5. Synthesis and Characterization of the First Group 2 Mixed .beta.-Diketonate Alkoxide Complexes. X-ray Crystal Structures of [Ca4(tmhd)4(OEt)4(EtOH)4], [Ca4(tmhd)6(OCH2CH2NMe2)2], and [H2Ba4(tmhd)6(OCH2CH2OPri)4]

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