1. Leptosperols A and B, Two Cinnamoylphloroglucinol–Sesquiterpenoid Hybrids from Leptospermum scoparium: Structural Elucidation and Biomimetic Synthesis
2. Total Synthesis of Leptosperol B through Stereocontrolled Intramolecular 1,4-Addition to Construct the Octahydronaphthalene Framework
3. Note on the Preparation of 1,2-Diketones from Acetylenes
4. See Supplementary Material in Detail.
5. Considering that the Z-olefin in 15 was generated as a result of anti-elimination, it is predicted that the stereochemistry of the secondary alcohol at the upper side would be S-configuration: see Supplementary Material in detail. Although it is unknown which is thermodynamically more stable, E or Z olefin on the upper side, we attempted photoisomerization (Z→E) on compound 15, which resulted in decomposition.