Water-trapping of unstable carbocations taking place into the inverted region of the Marcus equation. First experimental and computational evidence

Author:

Martínez Antonio García,de la Moya Cerero Santiago,Teso Vilar Enrique,García Fraile Amelia

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference44 articles.

1. Carbocation Chemistry;Olah,2004

2. 100 Years of Carbocations and Their Significance in Chemistry1

3. Cage Hydrocarbons;Olah,1990

4. Advance in Carbocation Chemistry;Della,1995

5. Carbocation Chemistry;Vogel,1985

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1. About the Existence of Organic Oxonium Ions as Mechanistic Intermediates in Water Solution;The Journal of Physical Chemistry A;2016-09-01

2. Carbocations;Organic Reaction Mechanisms Series;2015-06-02

3. Fundamental Flaw of Marcus Theory;CHEM J CHINESE U;2013

4. The Mechanism of Hydrolysis of Aryldiazonium Ions Revisited: Marcus Theory vs. Canonical Variational Transition State Theory;European Journal of Organic Chemistry;2013-08-01

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