Formation of 2-halomethylene-4-cyclopentene-1,3-diones and/or 2-halo-1,4-benzoquinones via ring-expansion of 4-ethynyl-4-hydroxy-2,3-substituted-2-cyclobuten-1-ones. Total synthesis of methyl linderone-Reference-Cited by-同舟云学术

Formation of 2-halomethylene-4-cyclopentene-1,3-diones and/or 2-halo-1,4-benzoquinones via ring-expansion of 4-ethynyl-4-hydroxy-2,3-substituted-2-cyclobuten-1-ones. Total synthesis of methyl linderone

Published:2013-11 Issue:44 Volume:69 Page:9284-9293
ISSN:0040-4020
Container-title:Tetrahedron
language:en
Short-container-title:Tetrahedron

Author:

Yin Hong,Dantale Shubhada W.,Akhmedov Novruz G.,Söderberg Björn C.G.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference25 articles.

1. Rearrangement of 4-alkynylcyclobutenones. A new synthesis of 1,4-benzoquinones

2. Synthesis of hydroxyquinones and related compounds: semisquaric acids, (.+-.)-terreic acid, (.+-.)-perezone and (.+-.)-isoperezone

3. A stereoselective, palladium-catalyzed route to 4-oxygenated 5-alkylidenecyclopentenones and 3-oxygenated 2-alkylideneindanones

4. Formation of 2-[1-(Trimethylsilyl)alkylidene]-4-cyclopentene-1,3-dione from Lewis Acid-Catalyzed Reaction of Cyclobutenedione Monoacetal with Alkynylsilane: Novel Cationic 1,2-Silyl Migrative Ring Opening and Subsequent 5-Exo-Trig Ring Closure

5. Unexpected Ionic Rearrangement of Hypoiodite. Ring-Expansion of 4-Alkynyl-4-hydroxycyclobutenone to Iodomethylenecyclopentene-1,3-dione

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