Solution and solid state conformation of Fischer carbene complexes vis-à-vis conformation of aryl carboxamides: complexation of the aromatic ring by tricarbonylchromium makes a difference

Author:

Jayaprakash K.N,Hazra Debasis,Hagen Karl S,Samanta Uttamkumar,Bhadbhade Mohan M,Puranik Vedavati G,Sarkar Amitabha

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference17 articles.

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2. Direct Observation of Orthogonal Orientation of an Aromatic Ring Attached to the Carbene Carbon in Fischer Carbene Complexes in Solution:  Diastereotopicity of Benzyl Protons as a Stereochemical Probe

3. (a) U. Schubert, Coordination Chemistry Review 55 (1984) 261. (b) K.H. Dötz, H. Fischer, P. Hofmann, F.R. Kreissel, U. Schubert, K. Weiss, Transition Metal Carbene Complexes, Verlag Chemie:Weinneim, 1983. For a few α, β-unsaturated carbene complexes characterized by crystallography, the π- plane is found to be coplanar. (c) B.A. Anderson, W.D. Wulff, T.S. Powers, S. Tribbitt, A.I. Rheingold, J. Am. Chem. Soc. 114 (1992) 10784. (d) G. Huttner, S. Lange, Chem. Ber. 103 (1970) 3149.

4. (a) M.J. Aroney, R.M. Clarkson, R.J. Klepetko, A.F. Mastens, R.K. Pierens, J. Organomet. Chem. 393 (1990) 371. (b) M.J Aroney, M.K Cooper, R.K.Pierens, S.J Pratten, J. Organomet. Chem. 307 (1986) 191. (c) M.J. Aroney, M.K. Cooper, R.K. Pierens, S.J. Pratten, J. Organomet. Chem. 295 (1985) 333. (d) N.A. Ogorodnikova, D.N. Kravtsov, Polyhedron, 9 (1990) 1.

5. The mechanisam of electrochemical reduction of N-haloamides in acetonitrile: trapping of intermediate amide anions and father–son protonation

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