Eleven-vertex polyhedral metalladicarbaborane chemistry. Reactions of neutral nido-5,6-C2B8H12 and the [nido-6,9-C2B8H10]2− anion to give formally closo isomeric 1-(arene) and 1-(cyclopentadiene)-1,2,4- and 1,2,3-metalladicarbaundecaboranes, and some substituent chemistry. Chiral separations, and crystal and molecular structures of [5-Br-1-(η6-C6Me6)-1,2,4-RuC2B8H9] and [2-Me-1-(η5-C5Me5)-1,2,3-RhC2B8H9]-Reference-Cited by-同舟云学术

Eleven-vertex polyhedral metalladicarbaborane chemistry. Reactions of neutral nido-5,6-C2B8H12 and the [nido-6,9-C2B8H10]2− anion to give formally closo isomeric 1-(arene) and 1-(cyclopentadiene)-1,2,4- and 1,2,3-metalladicarbaundecaboranes, and some substituent chemistry. Chiral separations, and crystal and molecular structures of [5-Br-1-(η6-C6Me6)-1,2,4-RuC2B8H9] and [2-Me-1-(η5-C5Me5)-1,2,3-RhC2B8H9]

Published:2000-12 Issue: Volume:614-615 Page:269-282
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Bown Mark,Grüner Bohumı́r,Štı́br Bohumil,Fontaine Xavier L.R.,Thornton-Pett Mark,Kennedy John D.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference105 articles.

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2. Oxidation of 7,8-dicarba-nido-undecaborate to 5,6-dicarba-nido-decaborane(12) and its dehydrogenation to 1,2-dicarba-closo-decaborane(10)

3. A convenient route to carbon-substituted derivatives of nido-5,6-C2B8H121Dedicated to Professor K. Wade on the occasion of his 65th birthday for his essential contributions to the area of cluster boron chemistry. All cluster chemists know Wade's electron-counting rules and use them for the benefit of chemistry.1

4. A Return to the Plesek Reaction and Some Useful Variations. Carbon-Substituted Methyl and Phenyl Derivatives of 5,6-Dicarba-nido-decaborane(12), nido-5,6-C2B8H12

5. Chemistry of boranes. XXX. Some reactions of 5,6-dicarba-nido-decaborane(12)

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