Synthesis and X-ray crystal structures of phosphido-bridge heterobimetallic complexes: [FeIr(μ-CO)(CO)4(μ-PtBu2)(tBu2PH)] and [CoIr(CO)5(μ-H)(μ-PtBu2)(tBu2PH)]-Reference-Cited by-同舟云学术

Synthesis and X-ray crystal structures of phosphido-bridge heterobimetallic complexes: [FeIr(μ-CO)(CO)4(μ-PtBu2)(tBu2PH)] and [CoIr(CO)5(μ-H)(μ-PtBu2)(tBu2PH)]

Published:1996-11 Issue:1-2 Volume:525 Page:191-197
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Böttcher H.-C.,Graf Marion,Merzweiler Kurt

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference17 articles.

1. Structure and bonding of the coordinatively unsaturated complexes [Fe2(CO)5(.mu.-PR2)(.mu.-PR'2)](Fe = Fe) (R = R' = CMe3; R = Ph, R' = CMe3). Reaction of Na[Fe2(.mu.-CO)(CO)6(.mu.-PR2)] with R'2PCl, (R, R'= Ph, Cy, Me, CMe3)

2. Ein ungewöhnliches Paar Bis(phosphido)‐verbrückter Dieisencarbonylkomplexe: [Fe 2 (CO) n {μ‐P( t Bu) 2 }(μ‐PCy 2 )] ( n = 5 und 6)

3. Synthese, charakterisierung und reaktivität heterodinuklearer komplexe: [(CO)4(μ-PtBu2)Rh(CO)L](Fe-Rh) (L = CO2, HPtBu2), [(CO)3,Co(μ-H)(μ-PtBu2)Rh(CO)(HPtBu2)](Co-Rh)

4. X-ray crystal structure of [FeRh(CO)6(μ-PtBu2)](FeRh): a molecule with two semibridging carbonyl ligands

5. H.-C. Böttcher, M. Graf and K. Merzweiler, submitted to Polyhedron.

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