Thermal reactions of alkyl(hydrido)(hydrosilyl)iridium(III) complexes: generation of a hydrido(silylene)iridium(I) species via the reductive elimination of alkane and 1,2-H-shift from the silicon atom to the Ir(I) metal center-Reference-Cited by-同舟云学术

Thermal reactions of alkyl(hydrido)(hydrosilyl)iridium(III) complexes: generation of a hydrido(silylene)iridium(I) species via the reductive elimination of alkane and 1,2-H-shift from the silicon atom to the Ir(I) metal center

Published:1998-02 Issue:1-2 Volume:553 Page:1-13
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Okazaki Masaaki,Tobita Hiromi,Kawano Yasuro,Inomata Shinji,Ogino Hiroshi

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference30 articles.

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2. T.D. Tilley, The Silicon-Heteroatom Bond, in: S. Patai, Z. Rappoport (Eds.), Wiley, New York, 1991, pp. 245 and 309.

3. J.Y. Corey, Advances in Silicon Chemistry, in: G. Larson (Ed.), JAI Press, Greenwich, CT, 1991, p. 327.

4. Redistribution Reactions on Silicon Catalyzed by Transition Metal Complexes

5. Reversible intramolecular base-stabilization in silylene (silanediyl) complexes: surprising reactivity for silylene coordination compounds with a dynamic N.cntdot..cntdot..cntdot.Si.cntdot..cntdot..cntdot.N bond

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