The oxidative addition of a vinylic CH bond of divinyl(phenyl)phosphine at M3(CO)12 carbonyls (M Ru, Os). Stepwise formation and crystal structure of [(μ-H)Ru3(CO)8{PPh(CHCH2)2}{μ3-PPh(CHCH2) (CHCH)}]
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference32 articles.
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5. Chemistry of multi-site bound unsaturated ligands on metal carbonyl clusters. Intramolecular reductive coupling in the conversion of [Ru3(µ-H)(CO)9(µ3,η2-CCBut)] to the butadienyl cluster [Ru3(CO)8{µ3,η4C(But)CC(H)C(Ph)(PPh2)}], and its crystal structure. An example of ligand isomerism on metal clusters
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4. Synthesis, characterization and reactivity of dinuclear rhenium complexes containing hemilabile phosphines as ligands: X-ray structures of diax-[Re2(CO)8{κ1(P)-Ph2P(CH2)2CN}2], [Re2(CO)8{μ:κ3(P,C,C)-iPr2NP(CH2CHCH2)2}] and diax-[Re2(CO)8(PPh3){κ1(P)-p-MeOC6H4P(CH2CHCH2)2}];Inorganica Chimica Acta;2016-01
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