Stereoselective synthesis and reactivity of cis- and trans- dimolybdenum nitrosyl derivatives with the bridging bis(dimethylsilanediyl)di(η5-cyclopentadienyl) ligand. X-ray molecular structures of cis-[Mo(CO)2(NO)2μ-(η5-C5H3)2(SiMe2)2], trans-[Mo(CO)(NO)(CNtBu)2μ-(η5-C5H3)2(SiMe2)2], cis-[Mo2(CO)3(NO)2(PMe3)μ-(η5-C5H3)2(SiMe2)2] and trans-[Mo(NO)(CNtBu)22μ-(η5-C5H3)2(SiMe2)2]-Reference-Cited by-同舟云学术

Stereoselective synthesis and reactivity of cis- and trans- dimolybdenum nitrosyl derivatives with the bridging bis(dimethylsilanediyl)di(η5-cyclopentadienyl) ligand. X-ray molecular structures of cis-[Mo(CO)2(NO)2μ-(η5-C5H3)2(SiMe2)2], trans-[Mo(CO)(NO)(CNtBu)2μ-(η5-C5H3)2(SiMe2)2], cis-[Mo2(CO)3(NO)2(PMe3)μ-(η5-C5H3)2(SiMe2)2] and trans-[Mo(NO)(CNtBu)22μ-(η5-C5H3)2(SiMe2)2]

Published:1997-12 Issue:2 Volume:548 Page:157-175
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Calvo Mercedes,Galakhov Mikhail V.,Gómez-García Roberto,Gómez-Sal Pilar,Martin Avelino,Royo Pascual,Vázquez de Miguel Amelio

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference25 articles.

1. Monocyclopentadienyl-type titanium complexes with the [.eta.5-.eta.5-(C5H4)2SiMe2]2- ligand. X-ray crystal structure of [(TiCl)2(.mu.2-O){.mu.2-.eta.5-.eta.5-(C5H4)2SiMe2}]2(.mu.2-O)2. The first example of a nonplanar titanium oxide ["Ti4O4"] core

2. Dinuclear titanium metallocene-type complexes with the bridging (dimethylsilylidene)bis(cyclopentadienyl) ligand. X-ray structures of [{TiCl2(.eta.5-C5Me5)}2{.mu.-.eta.5-.eta.5-(C5H4)2SiMe2}] and of [{TiCl(.eta.5-C5H5)}2(.mu.-O){.mu.-.eta.5-.eta.5-(C5H4)2SiMe2}]

3. Synthesis of bimetallic complexes of molybdenum containing bis(.eta.5-cyclopentadienyl)dimethylsilane or bis(.eta.5-tetramethylcyclopentadienyl)dimethylsilane bridges. Crystal structure of [{Mo(CO)3Cl}2-.mu.-(.eta.5-C5H4)2SiMe2]

4. Double-Dimethylsilyl-Bridged Dicyclopentadienyl Group 4 Metal Complexes. X-ray Molecular Structures of M[(Me2Si)2(.eta.5-C5H3)2]Cl2 (M = Ti, Zr) and (TiCl3)2{.mu.-[(Me2Si)2(.eta.5-C5H3)2]}

5. Stereoselective Synthesis of cis and trans Isomers of[{Mo(CO)3Cl}2{.mu.-.eta.5:.eta.5-(C5H3(SiMe2))2}]

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