Synthesis and structural analysis of the mixed-ligand seven-coordinate complexes [MI2(CO)2{P(OR)3}{Ph2P(CH2)nPPh2}] (M=Mo, R=Me, Et, n=1; R=Et, iPr, Ph, n=2; M=W, R=Ph, n=1; R=Me, Et, iPr, n=2). A system where the ligand cone angle and ligand ‘bite’ angle do not affect the coordination geometry-Reference-Cited by-同舟云学术

Synthesis and structural analysis of the mixed-ligand seven-coordinate complexes [MI2(CO)2{P(OR)3}{Ph2P(CH2)nPPh2}] (M=Mo, R=Me, Et, n=1; R=Et, iPr, Ph, n=2; M=W, R=Ph, n=1; R=Me, Et, iPr, n=2). A system where the ligand cone angle and ligand ‘bite’ angle do not affect the coordination geometry

Published:1999-11 Issue:1 Volume:590 Page:77-87
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Baker Paul K,Drew Michael G.B,Johans Archie W,Haas Ulrike,Latif Latifah Abdol,Meehan Margaret M,Zanin Sabrina

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference28 articles.

1. J. Lewis, R. Whyman, J. Chem. Soc. (1965) 5486.

2. Carbonyl halides of the Group VI transition metals. III. Tungsten halocarbonyls and some of their derivatives

3. J.R. Moss, B.L. Shaw, J. Chem. Soc. A (1970) 595.

4. Electrophilic and oxidative addition reactions of tungsten thiocarbonyl complexes

5. Halogen derivatives of triphenylphosphine, triphenylarsine and triphenylstibine substituted molybdenum carbonyls

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5. Synthesis and reactions of the cationic seven-coordinate complexes, [MoI(CO)3(NCR){Ph2P(CH2)nPPh2}][BF4] (R=Me, n=1, 2 and 3; R=Et, n=1). Crystal structures of [MoI2(CO)2(PPh3){Ph2P(CH2)PPh2}], [MoI(CO)2{Ph2P(CH2)PPh2}2][BF4]·CH2Cl2, [MoCl3O{Ph2PO(CH2)OPPh2}] and [Mo3(μ3-I)2{μ2-Ph2P(CH2)PPh2}3]I;Journal of Organometallic Chemistry;2002-12