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The synthesis of alkyl niobocene imido complexes and the X-ray crystal structure of [Nb(O)Cp2Me] (Cp=η5-C5H5)

  • Published:2001-08 Issue:1-2 Volume:631 Page:151-156
  • ISSN:0022-328X
  • Container-title:Journal of Organometallic Chemistry
  • language:en
  • Short-container-title:Journal of Organometallic Chemistry

Author:

Antiñolo Antonio,López-Solera Isabel,Otero Antonio,Prashar Sanjiv

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference32 articles.

1. See, for example: (a) D.N. Williams, J.P. Mitchell, A.D. Poole, U. Siemeling, W. Clegg, D.C.R. Hockless, P.A. O'Neil, V.C. Gibson, J. Chem. Soc. Dalton Trans. (1992) 739;(b) V.C. Gibson, D.N. Williams, W. Clegg, D.C.R. Hockless, Polyhedron 8 (1989) 1819;(c) U. Siemeling, V.C. Gibson, J. Organomet. Chem. 426 (1992) C25;(d) V.C. Gibson, A.D. Poole, U. Siemeling, D.N. Williams, W. Clegg, D.C.R. Hockless, J. Organomet. Chem. 462 (1993) C12;(e) T.C. Baldwin, S.R. Huber, M.A. Bruck, D.E. Wigley, Inorg. Chem. 32 (1993) 5682;(f) A.D. Poole, V.C. Gibson, W. Clegg, J. Chem. Soc. Chem. Commun. (1992) 237;(g) J.K. Cockcroft, V.C. Gibson, J.A.K. Howard, A.D. Poole, U. Siemeling, C. Wilson, J. Chem. Soc. Chem. Commun. (1992) 1668;(h) M.C.W. Chan, J.M. Cole, V.C. Gibson, J.A.K. Howard, C. Lehmann, A.D. Poole, U. Siemeling, J. Chem. Soc. Dalton Trans. (1998) 103;(i) M.L.H. Green, J.T. James, J.F. Saunders, J. Souter, J. Chem. Soc. Dalton Trans. (1997) 1281.

2. See, for example: (a) A.N. Chernega, M.L.H. Green, A.G. Suarez, J. Chem. Soc. Dalton Trans. (1993) 3031;(b) S. Schmidt, J. Sundermeyer, J. Organomet. Chem. 472 (1994) 127;(c) M.L.H. Green, J.T. James, A.N. Chernega, J. Chem. Soc. Dalton Trans. (1997) 1719;(d) W.A. Hermann, W. Baratta, E. Herdtweck, Angew. Chem. Int. Ed. Engl. 35 (1996) 1951;(e) A.N. Chernega, M.L.H. Green, A.G. Suarez, Can. J. Chem. 73 (1995) 1157.

3. Synthesis and reactivity of bis(trimethylsilylcyclopentadienyl)- niobium compounds with cumulene ligands

4. Synthesis and structural characterisation of new isocyanate and imido niobocene complexes. Crystal structures of [{Nb(η-C5H4SiMe3)2Cl}2] and [Nb(η-C5H4SiMe3)2(=NPh)Cl]

5. Electrocatalytic process in the reduction of Nb[η5-C5H4(SiMe3)]2(Cl)(NHPh)BF4

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