The deviating behavior of thiols in nucleophilic trapping reactions of chromiumcarbonyl phenyl complex substituted propargyl cation

Author:

Netz Astrid,Polborn Kurt,Müller Thomas J.J.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference48 articles.

1. For reviews see e.g.: (a) L. Haynes, R. Pettit, in: G.A. Olah, P.v.R. Schleyer (Eds.), Carbonium Ions, Wiley, New York, 1975, p. 5;(b) W.E. Watts, G. Wilkinson, F.G.A. Stone, E.W. Abel (Eds.), Comprehensive Organometallic Chemistry, vol. 8, Pergamon, Oxford, 1982, p. 1051, Chapter 59;(c) A. Solladié-Cavallo, Polyhedron 4 (1985) 901;(d) G. Jaouen, Pure Appl. Chem. 58 (1986) 597;(e) K.M. Nicholas, Acc. Chem. Res. 20 (1987) 207. For stabilization of positive charge in benzylic positions by chromium carbonyl fragments;(f) S.G. Davies, T.J. Donohoe, Synlett (1993) 323.

2. Arene-metal complexes. II. Thermodynamic stabilities of .alpha.-substituted .alpha.-hydroxybenzyl cations complexed with tricarbonylchromium. The variable cation-stabilizing ability of the tricarbonylchromium moiety

3. Organometallic chemistry. 9. Carbon-13 nuclear magnetic resonance study of the cumylchromium tricarbonyl and of cycloheptatrienylmolybdenum (-chromium, and -tungsten) tricarbonyl cations

4. Metal-stabilized carbonium ions derived from bis(tricarbonylchromium) complexes of diarylmethanes

5. Correlation of the reactivity of coordinated π-hydrocarbons with electronic parameters

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