The functionalization of saturated hydrocarbons. Part 35. On the intermediates in an FeIII catalase model in pyridine. Relevance to the catalase enzyme
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference35 articles.
1. Cytochrome P-450: Structure, Mechanism and Biochemistry;Marnett,1986
2. Recent Developments in the Redox Chemistry of Peroxides
3. Fenton reagents (1:1 FeIILx/HOOH) react via [LxFeIIOOH(BH+)] (1) as hydroxylases (RH .fwdarw. ROH), not as generators of free hydroxyl radicals (HO.bul.)
4. Aromatic hydroxylation by fenton reagents {Reactive intermediate[Lx+FeIIIOOH(BH+)], not free hydroxyl radical (HO·)}
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