Investigation of the diastereofacial selectivity of the addition of 1-metalated (E)- and (Z)-hept-1-enes to the COREY aldehyde — A comparison between vinyllithium and vinyltitanium compounds1,2
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference20 articles.
1. Complete transfer of chirality in the [3,3]-sigmatropic rearrangement of allylic acetates catalyzed by palladium(II). Application to stereocontrolled syntheses of prostaglandins possessing either the C-15(S) or C-15(R) configuration
2. Synthesis of novel prostaglandin F2α isomers and structure of an enzymatically formed 13-hydroxyprostaglandin endoperoxide
3. Novel stereospecific silyl group transfer reactions: practical routes to the prostaglandins
4. The diastereofacial selectivity of the addition of various 1-metalated 1-heptynes to substituted cyclopentanecarbaldehydes. - The use of 1-titanated 1-heptyne for the construction of the alkyl side chain of Prostaglandins
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