Asymmetric Syntheses of (2S,3S,6S)-, (2S,3S,6R)-, and (2R,3R,6S)-2,3-Methano-2,6-diaminopimelic Acids. Studies Directed to the Design of Novel Substrate-based Inhibitors of L,L-Diaminopimelate Epimerase-Reference-Cited by-同舟云学术

Asymmetric Syntheses of (2S,3S,6S)-, (2S,3S,6R)-, and (2R,3R,6S)-2,3-Methano-2,6-diaminopimelic Acids. Studies Directed to the Design of Novel Substrate-based Inhibitors of L,L-Diaminopimelate Epimerase

Published:1996-01 Issue:4 Volume:52 Page:1149-1164
ISSN:0040-4020
Container-title:Tetrahedron
language:en
Short-container-title:Tetrahedron

Author:

Williams Robert M.,Fegley Glenn J.,Gallegos Reneé,Schaefer Felicity,Pruess David L.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference49 articles.

1. Purification and properties of diaminopimelic acid epimerase from Escherichia coli.

2. The stereoisomers of α∈-diaminopimelic acid. 3. Properties and distribution of diaminopimelic acid racemase, an enzyme causing interconversion of the ll and meso isomers

3. Energetics of proline racemase: tracer perturbation experiments using [14C]proline that measure the interconversion rate of the two forms of free enzyme

4. Energetics of proline racemase: transition-state fractionation factors for the two protons involved in the catalytic steps

5. Energetics of proline racemase: double fractionation experiment, a test for concertedness and for transition-state dominance

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