The rate and mechanism of oxidative addition of H2 to the Cr(CO)3C5Me5 radical—generation of a model for reaction of H2 with the Co(CO)4 radical

Author:

Capps Kenneth B.,Bauer Andreas,Kiss Gabor,Hoff Carl D.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference31 articles.

1. Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals

2. Oxidative Addition of Thiols, Disulfides, Iodine, and Hydrogen Iodide to W(CO)3(PiPr3)2. Preparation of Stable 17-Electron Tungsten Thiolate Radicals from Complexes with Weak W-H Bonds

3. Kinetics of the reactions of (ethoxycarbonyl)methylcobalt tetracarbonyl with carbon-13 monoxide, triphenylphosphine, hydridocobalt tetracarbonyl, and hydrogen. A comparison of the reactivities of (ethoxycarbonyl)methyl-, ethoxycarbonyl-, and hydridocobalt tetracarbonyl complexes

4. Following several months of experimental work and preparation of a rough draft of the work in Ref. [3], C.D.H. recalls presenting the manuscript to Professor Ungváry who said: “Give it to Laci, let him do his work. You will see, he will come up with a good idea”. The most remarkable aspect of the work—the significance of the very slow rate of reaction of H2 with RCo(CO)4 and how it depended on R—was first noted by Professor Markó. The ‘good idea’ turned out to be addition of the brief statement ‘steric factors can hardly play a role in determining the reactivity toward H2; the effect has to be primarily electronic in origin’.

5. 19-Electron organometallic adducts

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