Ruthenium(II) complexes containing both arene and functionalized phosphines. Synthesis and catalytic activity for the hydrogenation of styrene and phenylacetylene-Reference-Cited by-同舟云学术

Ruthenium(II) complexes containing both arene and functionalized phosphines. Synthesis and catalytic activity for the hydrogenation of styrene and phenylacetylene

Published:1998-09 Issue:1-2 Volume:566 Page:165-174
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Moldes Isabel,de la Encarnación Esther,Ros Josep,Alvarez-Larena Ángel,Piniella Joan F

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference37 articles.

1. Reactions of Ru(CO)HCl(PPh3)3 with activated mono- and disubstituted acetylenes. Crystal structure of [cyclic] [(PPh3)2(CO)(MeO2CC.tplbond.C)Ru(MeOOCC:CHCH:CHCO2Me)]

2. Reaction of alkenyl-ruthenium(II) Ru(CO)Cl(RC=CHR′(PPh3)2 complexes with CO. Formation of dicarbonyl complexes or η2-acyl complexes depending on the R and R′ groups

3. The formation of alkenedithiocarboxylate and alkenecarboxylate ligands by insertion of CS2 and CO2 into ruthenium(II)alkenyl bonds

4. Insertion of carbon disulfide into ruthenium-alkenyl bonds. Formation of an alkene dithiocarboxylate ligand

5. Insertion reactions of dimethyl acetylenedicarboxylate with alkenylruthenium complexes of the type [Ru(CO)Cl(R′CCHR)(PPh3)2]. The crystal structure of [RCCC(CO2Me)-CHCHCMe3}(PPh3)2]

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