A 29Si, 13C and 1H NMR study of the interaction of various halotrimethylsilanes and trimethylsilyl triflate with dimethyl formamide and acetonitrile, a comment on the nucleophile induced racemisation of halosilanes-Reference-Cited by-同舟云学术

A 29Si, 13C and 1H NMR study of the interaction of various halotrimethylsilanes and trimethylsilyl triflate with dimethyl formamide and acetonitrile, a comment on the nucleophile induced racemisation of halosilanes

Published:1982-11 Issue:4 Volume:238 Page:C41-C45
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Bassindale Alan R,Stout Tim

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference9 articles.

1. The nature of the interaction of nucleophiles such as HMPT, DMSO, DMF and Ph3PO with triorganohalo-silanes, -germanes, and -stannanes and organophosphorus compounds. Mechanism of nucleophile induced racemization and substitution at metal

2. The nature of the interaction between hexamethyl-phosphortriamide and trimethylhalosilanes; cations containing tetracovalent silicon as possible intermediates in nucleophile-induced substitution of silicon halides

3. Solvent-induced isomerization of halosilacyclobutanes. A mechanism with ionic intermediates with expanded coordination

4. Solvent-catalyzed cis-trans isomerization of halosilacyclo-butanes and -pentanes. Evidence for cationic intermediates with expanded coordination

5. Mécanisme de l'hydrolyse des chlorosilanes, catalysée par un nucléophile: étude cinétique et mise en evidence d'un intermediaire hexacoordonné

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