Synthesis and structural characterization of (THF)3Na{(SnC6H3–2,6-Trip2)2} (Trip=C6H2-2,4,6-i-Pr3): effects of cation–anion association on Sn–Sn multiple bonding

Author:

Pu Lihung,Haubrich Scott T,Power Philip P

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference11 articles.

1. Synthesis and Characterization of [Sn2{C6H3-2,6(2,4,6-i-Pr3C6H2)2}2]-•:  A Singly Reduced Valence Isomer of a “Distannyne”

2. K. Ruhlandt-Senge, J.J. Ellison and R.J. Wehnschulte, F. Pauer, P.P. Power, J. Am. Chem. Soc. 115 (1993) 11353; J.J. Ellison, P.P. Power, Inorg. Chem. 34 (1994) 4231; X.-W. Li, W.T. Pennington, G.H. Robinson, J. Am. Chem. Soc. 117 (1995) 7578; B. Schiemenz, P.P. Power, Angew. Chem. Int. Ed. Engl. 35 (1996) 2150; M. Niemeyer, P.P. Power, Inorg. Chem. 35 (1996) 7264.

3. The Use of Density Functional Theory To Understand and Predict Structures and Bonding in Main Group Compounds with Multiple Bonds

4. The Na–Ph interactions in this compound are thought [3] to be partially responsible for the relatively short, calculated Ga–Ga distance of 2.36 Å. This bond length is in reasonable agreement with the ca. 2.32 Å Ga–Ga distance observed in Na2(GaC6H3–2,6-Trip2)2: J. Su, X–W Li, R.C. Crittendon, G.H. Robinson, J. Am. Chem. Soc. 119 (1997) 547.

5. This method is described by H.A Hope, Practicum, synthesis and characterization, in: A.L. Wayda, M.Y. Darensbourg (Eds.), Experimental Organometallic Chemistry, Chapter 10, ACS Symposium Series 357; American Chemical Society, Washington, DC, 1987.

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