Übergangsmetallkomplexe mit Schwefelliganden CXXIV. Koordination von C- und S-Liganden an Metall—Carben—Thiolat-Fragmente [M(‘S2C’)] [M = NiII, PdII, PtII; ‘S2C’2− = 1,3-Imidazolidinyl-N,N′-bis(2-benzolthiolat)(2 −)]. [M(L)(‘S2C’)]-Komplexe mit L = CN−, CH3−, COCH3−, CNBu, CR2, SH− und SR− (R = Et, Ph, o-C6H4NH2)

Author:

Sellmann Dieter,Allmann Christof,Heinemann Frank,Knoch Falk,Sutter Jörg

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference46 articles.

1. D. Sellmann, T. Gottschalk-Gaudig, F. Heinemann, F. Knoch, Chem. Ber., eingereicht.

2. Homogeneous Catalysis;Parshall,1992

3. Bioinorganic Catalysis;Reedijk,1993

4. Acetogenesis;Drake,1994

5. Transition-metal complexes with sulfur ligands. 89. Unexpected formation of the highly stable binuclear nickel carbene complex [Ni(S2C)]2 from nickel(II) salts, diamine-dithiolate ligands, and C1 components [S2C2- = 1,3-imidazolidine-1,3-diylbis(2-benzenethiolate)(2-)]

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