The reaction of alkynes with dichloroborane ethyl etherate in the presence of boron trichloride. A simple, general synthesis of alkenyldichloroboranes-Reference-Cited by-同舟云学术

The reaction of alkynes with dichloroborane ethyl etherate in the presence of boron trichloride. A simple, general synthesis of alkenyldichloroboranes

Published:1973-11 Issue: Volume:61 Page:C5-C7
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Brown Herbert C.,Ravindran N.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference5 articles.

1. Organoboron Halides. II. The Vinylhaloboranes, A Preliminary Study of their Preparation and Properties1,2

2. Vinyl Derivatives of some Metals and Nonmetals

3. Reaction of alkenylboronic acids with iodine under the influence of base. Simple procedure for the stereospecific conversion of terminal alkynes into trans-1-alkenyl iodides via hydroboration

4. Stereospecific conversion of alkenylboronic acids into alkenyl bromides with inversion of configuration. Striking differences in the stereochemistry of the replacement of the boronic acid substituent by bromine and iodine and its significance in terms of the reaction mechanism

5. Reaction of representative olefins with dichloroborane ethyl etherate induced by boron trichloride. Exceptionally simple, general synthesis of alkyldichloroboranes and alkylboronic acid derivatives via hydroboration

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1. Dichloroborane diethyl etherate;Fieser and Fieser's Reagents for Organic Synthesis;2006-12-15

2. Synthesis of C2B3 X-Heterocycles (X = C, N, P, O, S) from 1,3,5-Triborapentanes;Zeitschrift für Naturforschung B;1997-07-01

3. A novel and efficient route to (E)-alk-1-enyl boronic acid derivatives from (E)-1-(trimethylsilyl)alk-1-enes and a formal Suzuki–Miyaura cross-coupling reaction starting with vinylsilanes;J. Chem. Soc., Chem. Commun.;1995

4. Non-cyclic Three and Four Coordinated Boron Compounds;Comprehensive Organometallic Chemistry;1982

5. Hydroboration. XLI. Hydroboration of alkenes and alkynes with dichloroborane etherates. Convenient procedures for the preparation of alkyl- and alkenyldichloroboranes and their derivatives;Journal of the American Chemical Society;1976-03