Stereoselective accesses to enantioenriched allyl-, allenyl-, and propargyl-silanes via SiSi bond activation by palladium–isocyanide catalysts
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference53 articles.
1. Fluorinated polysilanes. palladium-catalyzed disilane metathesis, double silylation of acetylenes, and the stereo chemical course
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3. Nickel-catalyzed additions of the SiSi bond of hydrodisilanes to 1,3-dienes and alkynes were reported earlier than those in Refs. [1,2]. Although these reactions are apparent prototypes of the bis-silylation reaction, they may proceed through oxidative addition of the SiH bond to Ni. H. Okinoshima, K. Yamamoto, M. Kumada, J. Am. Chem. Soc. 94 (1972) 26.
4. A novel double silylation of dimethyl acetylenedicarboxylate catalyzed by phosphinepalladium(II) complexes
5. Making and Breaking of SiE(E= C, Si) Bonds by Oxidative Addition and Reductive Elimination Reactions
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