EPR and 1H NMR spectroscopic characterization of the ferric species formed in the iron picolinate/(pyridine/acetic acid)/HOOH catalytic system for the direct ketonization of methylenic carbons-Reference-Cited by-同舟云学术

EPR and 1H NMR spectroscopic characterization of the ferric species formed in the iron picolinate/(pyridine/acetic acid)/HOOH catalytic system for the direct ketonization of methylenic carbons

Published:1996-10 Issue:2 Volume:112 Page:253-258
ISSN:1381-1169
Container-title:Journal of Molecular Catalysis A: Chemical
language:en
Short-container-title:Journal of Molecular Catalysis A: Chemical

Author:

Sobolev A.P.,Babushkin D.E.,Shubin A.A.,Talsi E.P.

Publisher

Elsevier BV

Subject

Physical and Theoretical Chemistry,Process Chemistry and Technology,Catalysis

Reference14 articles.

1. The selective functionalization of saturated hydrocarbons: Gif chemistry

2. The functionalization of saturated hydrocarbons. Part 20. Alkyl hydroperoxides: reaction intermediates in the oxidation of saturated hydrocarbons by Gif-type reactions and mechanistic studies on their formation

3. Fenton reagents (1:1 FeIILx/HOOH) react via [LxFeIIOOH(BH+)] (1) as hydroxylases (RH .fwdarw. ROH), not as generators of free hydroxyl radicals (HO.bul.)

4. Nature of the reactive intermediates from the iron-induced activation of hydrogen peroxide: agents for the ketonization of methylenic carbons, the monooxygenation of hydrocarbons, and the dioxygenation of aryl olefins

5. Iron-induced activation of hydrogen peroxide for the direct ketonization of methylenic carbon (cyclohexane .fwdarw. cyclohexanone) and the dioxygenation of acetylenes and aryl olefins

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1. Recent trends in non-noble metal-catalyzed hydroxylation reactions;Journal of Organometallic Chemistry;2022-10

2. Mechanistic implications of the active species involved in the oxidation of hydrocarbons by iron complexes of pyrazine-2-carboxylic acid;Dalton Transactions;2008

3. Kinetics of the Reaction of Mer-Tris(Picolinato) Iron(III) with Hydrogen Peroxide in Pyridine: Role of Hydroxyl Radicals in Subsequent Catalytic Oxygenation of Cyclohexane to the Ketone.;BioInorganic Reaction Mechanisms;2007-01-01

4. The oxygenation of cyclohexane under GifIV conditions – The catalytic behaviour of iron complexes;Inorganica Chimica Acta;2006-10

5. The reaction of [Fe(pic)3] with hydrogen peroxide: a UV-visible and EPR spectroscopic study (Hpic = picolinic acid);Dalton Transactions;2005